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内容提要:
This should prove to be the definitive work explaining van der Waals forces, how to calculate them and take account of their impact under any circumstances and conditions. These weak intermolecular forces are of truly pervasive impact, and biologists, chemists, physicists, and engineers will profit greatly from the thorough grounding in these fundamental forces. Parsegian has organized his book at three successive levels of mathematical sophistication, to satisfy the needs and interests of readers at all levels of preparation. The Prelude and Level 1 are intended to give everyone an overview in words and pictures of the modern theory of van der Waals forces. Level 2 gives the formulae and a wide range of algorithms to let readers compute the van der Waals forces under virtually any physical or physiological conditions. Level 3 offers a rigorous basic formulation of the theory.
目录:
List of tables
Preface PRELUDE Pr.1. The dance of the charges Pr.2. How do we convert absorption spectra to charge-fluctuation forces? Pr.3. How good are measurements? Do they really confirm theory? Pr.4. What can I expect to get from this book? LEVEL 1: INTRODUCTION L1.1. The simplest case: Material A versus material B across medium m L1.2. The van der Waals interaction spectrum L1.3. Layered planar bodies L1.4. Spherical geometries L1.5. Cylindrical geometries LEVEL 2: PRACTICE L2.1. Notation and symbols L2.1.A. Geometric quantities L2.1.B. Force and energy L2.1.C. Spherical and cylindrical bodies L2.1.D. Material properties L2.1.E. Variables to specify point positions L2.1.F. Variables used for integration and summation L2.1.G. Differences-over-sums for material properties L2.1.H. Hamaker coefficients L2.1.I. Comparison of cgs and mks notation L2.1.J. Unit conversions, mks-cgs L2.2. Tables of formulae L2.2.A. Tables of formulae in planar geometry L2.2.B. Tables of formulae in spherical geometry L2.2.C. Tables of formulae in cylindrical geometry L2.3. Essays on formulae L2.3.A. Interactions between two semi-infinite media L2.3.B. Layered systems L2.3.C. The Derjaguin transform for interactions between oppositely curved surfaces L2.3.D. Hamaker approximation: Hybridization to modern theory L2.3.E. Point particles in dilute gases and suspensions L2.3.F. Point particles and a planar substrate L2.3.G. Line particles in dilute suspension L2.4. Computation Lg.4.A. Properties of dielectric response L2.4.B. Integration algorithms L2.4.C. Numerical conversion of full spectra into forces Lg.4.D. Sample spectral parameters Lg.4.E. Department of tricks, shortcuts, and desperate necessities L2.4.F. Sample programs, approximate procedures LEVEL 3: FOUNDATIONS L3.1. Story, stance, strategy L3.2. Notation used in level 3 derivations L3.g.A. Lifshitz result L3.2.B. Layered systems L3.2.C. Ionic-fluctuation forces L3.2.D. Anisotropic media L3.2.E. Anisotropic ionic media L3.3. A heuristic derivation of kifshitz' general result for the interaction between two semi-infinite media across a planar gap L3.4. Derivation of van der Waals interactions in layered planar systems L3.5. Inhomogeneous media L3.6. Ionic-charge fluctuations L3.7. Anisotropic media Problem sets Problem sets for Prelude Problem sets for level 1 Problem sets for level 2 Notes Index |